Effect of Sulfuric Acid Immersion on the Carbon Characteristics of Cocoa Pod Husk

Octavia Marsha Pakpahan (1), Arya Widira Adi Nugraha (2), Susilowati (3), Caecilia Pujiastuti (4)
(1) 1Chemical Engineering Department, Faculty of Science and Technology, “Veteran” University of National Development East Java, Surabaya, Indonesia
(2) 1Chemical Engineering Department, Faculty of Science and Technology, “Veteran” University of National Development East Java, Surabaya, Indonesia
(3) 1Chemical Engineering Department, Faculty of Science and Technology, “Veteran” University of National Development East Java, Surabaya, Indonesia
(4) 1Chemical Engineering Department, Faculty of Science and Technology, “Veteran” University of National Development East Java, Surabaya, Indonesia
How to cite (AJARCDE) :
Pakpahan, O. M., Arya Widira Adi Nugraha, Susilowati, & Caecilia Pujiastuti. (2025). Effect of Sulfuric Acid Immersion on the Carbon Characteristics of Cocoa Pod Husk. AJARCDE (Asian Journal of Applied Research for Community Development and Empowerment), 9(3), 204–209. https://doi.org/10.29165/ajarcde.v9i3.815

Indonesia faces the challenge of dependency on fossil fuels, making the utilization of Biomass as a renewable energy source increasingly important. Cocoa pod husk, an abundant agricultural waste, has the potential to be converted into high-quality solid fuel through the torrefaction process. This study aims to analyze the effect of sulfuric acid (H?SO?) solution concentration and torrefaction temperature on the characteristics of carbon produced from cocoa pod husk, as well as to compare the results with the Indonesian National Standard (SNI) 8675-2018. The methods used include biomass preparation, soaking with various H?SO? concentrations (0, 0.4, 0.6, 0.8, and 1 M), and torrefaction at different temperatures (250, 275, 300, 325, and 350 °C). The product characteristics were analyzed using proximate analysis, calorific value testing, and SEM EDX. The results showed that increasing the acid concentration and torrefaction temperature significantly reduced the moisture, ash, and volatile matter content, while increasing the fixed carbon and calorific value. The optimum condition was obtained at 1 M H?SO?. soaking and 350 °C torrefaction, producing carbon with 0.17% moisture, 3.00% ash, 61.79% volatile matter, 35.04% fixed carbon, and a calorific value of 8071.34 cal/g. All parameters met the SNI 8675-2018 standard, indicating that acid-pretreated and torrefied cocoa pod husk has strong potential to be developed into high-quality solid fuel.


Contribution to Sustainable  Development Goals (SDGs)
SDG 7 (Affordable and Clean Energy)
SDG 12 (Responsible Consumption and Production)
SDG 13 (Climate Action)

[1] Badan Standardisasi Nasional. (2018). *SNI 8675:2018 - Bahan bakar padat dari biomassa*. Jakarta: BSN.

[2] Gumilar, Y. (2022). Pengaruh pretreatment asam terhadap karakteristik biomassa untuk aplikasi bahan bakar. Jurnal

Teknik Kimia Indonesia, 15(2), 45-56.

[3] Kementerian ESDM. (2023). Laporan kinerja sektor energi dan sumber daya mineral tahun 2023. Jakarta:

Kementerian ESDM RI.

[4] Loppies, J. (2016). Karakteristik karbon dari dekomposisi termal biomassa lignoselulosa. Jurnal Riset Teknologi

Industri, 10(1), 23-30.

[5] Maryenti, S. (2017). Pengaruh suhu torrefaksi terhadap karakteristik abu pada biomassa. Jurnal Teknologi Bahan

Alam, 8(3), 112-118.

[6] Pratama, R. (2021). Pretreatment kimia untuk reduksi kadar abu pada bahan bakar biomassa. Jurnal Energi

Terbarukan, 9(2), 67-74.

[7] Retwan, M.A.A., Ginting, Z., Muhammad, Syamsul Bahri, & Faisal. (2024). Pengaruh penggunaan larutan NaOH

dan CH3COOH terhadap karakteristik biobriket dari ampas kopi dengan proses hydrothermal. Chemical

Engineering Journal Storage, 4(5), 719-728.

[9] Sena, A. (2021). Komposisi kimia dan potensi kulit kakao sebagai bahan baku energi terbarukan. Jurnal Teknologi

Pertanian, 12(3), 89-95.

[10] Surono, U.B., & Hutomo, G.D. (2021). Torefaksi sebagai teknologi pretreatment biomassa untuk peningkatan kualitas bahan bakar padat. Jurnal Integrasi Proses, 15(1), 23-30.

[11] Wang, L., Skreiberg, Ø., Khalil, R., Corscadden, K., & Grønli, M. (2020). Structural and thermal changes of torrefied biomass during CO? gasification. Fuel Processing Technology, 197, 06189. https://doi.org/10.1016/j.fuproc.2019.106189

[12] Wenas, A. (2021). Pengaruh torrefaksi terhadap perendaman potassium dalam konversi tandan kosong kelapa sawit menjadi bahan bakar padat ramah lingkungan. Jurnal Material dan Proses Manufaktur, 5(2), 123-140.

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